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Mutated by humanity's nuclear waste, he arrives looking for more to raise his mutant liberation front army, I present Minkey.



Now gimme the goo!!!!

One thing that could help, that I'm surprised wasn't mentioned, is during the sketching phase, lightly sketch what is behind the stuff in the foreground. In your case, Spidey's waist to his hips, his neck and where his trapezius  muscle connects between the neck and the upper shoulder muscle (the deltoid). This should help get rid of that feel of different parts of the drawing floating on eachother.

Also I would suggest reading up on muscle anatomy since it is a huge part of drawing superheroes and villians. Comic book artists love drawing out muscles, makes the characters seem immensely powerful. Plus it will also help your art skills in other areas as well, even cartooning! (Trust me on that one, I've been banging my head against the wall on parts of my own art till I started taking anatomy seriously.)

All in all, I love the picture very dynamic and a very cool feel of perspective. I feel like I'm about to take a Spidey knee in the face just looking at it!  :o Can't wait to see the finished product.